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A brand-new battery labelled "1.5 V" never quite gives you 1.5 V once it’s actually driving a current — connect a voltmeter across its terminals under load and you’ll read a little less. The missing energy hasn’t vanished: every real source of e.m.f. has its own , and it dissipates some of its own energy pushing charge through itself before that charge ever reaches the rest of the circuit.
What you'll be able to do
The , , of a source is the total energy transferred to each unit of charge that passes through it — not just the energy delivered to the external circuit, but of it, including whatever is dissipated inside the source itself. Every real cell or battery has some , , arising from the resistance of the chemicals and materials the current must pass through inside the source.
Because current must flow through this internal resistance too, some of the e.m.f. is inevitably "used up" driving current through the source itself, before the charge ever reaches the external circuit. This lost energy per unit charge is called the , and what’s left over — the p.d. actually available across the external circuit — is the .
Tip — E.m.f. is measured with (effectively) no current flowing — that’s when there are no lost volts and the terminal p.d. equals the full e.m.f.
If the external resistance is reduced to zero (a direct short circuit across the terminals), the only resistance left in the circuit is the source’s own internal resistance. This gives the maximum possible current the source can ever deliver — and is exactly why short-circuiting a battery is dangerous: a large current flows, dissipating a lot of power inside the source itself, which can generate significant heat.
Rearranging in terms of the terminal p.d. gives — a straight-line equation if you plot terminal p.d. against current (varying the external resistance, for instance with a rheostat, to get several data points). The line has -intercept (the terminal p.d. you’d extrapolate to at zero current) and gradient (the internal resistance, as a negative slope).
This graphical method is a standard AQA required-practical technique: it finds both e.m.f. and internal resistance from a single set of readings, without ever needing to measure either directly, and it lets you assess the uncertainty in each from how well the data fits the line.
Tip — Don’t forget the minus sign: the gradient of the V–I graph is −r, so a gradient of −0.30 Ω means the internal resistance itself is +0.30 Ω.
Equation recap
Common mistakes to avoid
Key takeaways
Test yourself
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