31–32, 37, 41ElectricityFoundation

Charge, Current and Potential Difference

A circuit moves charge around a loop and transfers energy as it goes. Current\textbf{Current} measures how fast the charge flows; potential difference\textbf{potential difference} measures how much energy each coulomb gives up. Keeping those two ideas distinct is most of what makes circuits make sense.

35 min Topic 3 · Electric Circuits

What you'll be able to do

  • Define current as rate of flow of charge and use I=ΔQ/ΔtI = \Delta Q / \Delta t
  • Define potential difference and e.m.f. in terms of energy per unit charge
  • Use I=nAvqI = nAvq and interpret each quantity
  • Explain why a lamp lights immediately despite a very low drift velocity
1

Current as a rate of flow

Electric current is the rate of flow of charge: I=ΔQΔtI = \dfrac{\Delta Q}{\Delta t}. One ampere is one coulomb per second, and the ampere is an SI base unit — the coulomb is defined from it, not the other way round.

In a metal the charge carriers are free electrons, each carrying −1.60×10−19 C-1.60 \times 10^{-19}\ \mathrm{C}. Conventional current\textbf{Conventional current} is defined as flowing from positive to negative, which is opposite to the actual electron flow — a historical convention that predates the discovery of the electron and is now too entrenched to change.

Charge is quantised\textbf{quantised}: any charge is a whole-number multiple of the elementary charge ee. That is why the number of electrons is always a whole number in these calculations.

I=ΔQΔtI = \dfrac{\Delta Q}{\Delta t}
Current is rate of flow of charge.
Q=ItQ = It
Charge from a steady current.
e=1.60×10−19 Ce = 1.60 \times 10^{-19}\ \mathrm{C}
The elementary charge.
Example 1A current of 250 mA250\ \mathrm{mA} flows for 2 minutes. Find the charge transferred and the number of electrons.
1Convert: I=0.250I = 0.250 A, t=120t = 120 s.
2Q=It=0.250×120=30Q = It = 0.250 \times 120 = 30 C.
3Number of electrons: 301.60×10−19\dfrac{30}{1.60\times10^{-19}}.
AnswerQ=30 CQ = 30\ \mathrm{C}; about 1.9×10201.9 \times 10^{20} electrons.

Tip — Convert milliamps to amps and minutes to seconds before substituting. Mixed units here produce answers wrong by factors of 1000 or 60 with no warning.

2

Potential difference and e.m.f.

Potential difference\textbf{Potential difference} across a component is the energy transferred from\textit{from} the charge to that component, per coulomb: V=WQV = \dfrac{W}{Q}. One volt is one joule per coulomb.

Electromotive force\textbf{Electromotive force} is the same quantity for a source: the energy transferred to\textit{to} each coulomb by the cell. Despite its name it is not a force — it is measured in volts, and the misnomer is another historical leftover.

The distinction is direction of energy transfer. A cell gives energy to the charge (e.m.f.); a resistor takes energy from it (p.d.). Both are joules per coulomb.

V=WQV = \dfrac{W}{Q}
Potential difference: energy per coulomb delivered.
ε=WQ\varepsilon = \dfrac{W}{Q}
E.m.f.: energy per coulomb supplied.
W=QV=IVtW = QV = IVt
Energy transferred.
Example 1A 12 V battery drives a current of 2.0 A through a lamp for 5.0 minutes. Find the energy transferred.
1t=300t = 300 s, so Q=2.0×300=600Q = 2.0 \times 300 = 600 C.
2W=QV=600×12W = QV = 600 \times 12.
Answer7200 J7200\ \mathrm{J}, or 7.2 kJ7.2\ \mathrm{kJ}.
3

The drift velocity equation

Current depends on how many charge carriers there are, how fast they move, and how much charge each carries. Combining these gives I=nAvqI = nAvq, where nn is the number density of carriers (per cubic metre), AA the cross-sectional area, vv the mean drift velocity, and qq the charge per carrier.

The derivation is worth seeing: in time tt the carriers travel vtvt, so the volume passing a point is AvtAvt, containing nAvtnAvt carriers and therefore a charge nAvtqnAvtq. Dividing by tt gives the current.

The equation explains the difference between conductors, semiconductors and insulators. A metal has an enormous nn, around 1028 m−310^{28}\ \mathrm{m^{-3}}; a semiconductor has far fewer carriers; an insulator has almost none — which is why the same p.d. drives vastly different currents through them.

I=nAvqI = nAvq
Number density, area, drift velocity, charge.
v=InAqv = \dfrac{I}{nAq}
Rearranged for drift velocity.
Example 1A copper wire of cross-sectional area 1.0×10−6 m21.0 \times 10^{-6}\ \mathrm{m^{2}} carries 3.0 A. Copper has n=8.5×1028 m−3n = 8.5 \times 10^{28}\ \mathrm{m^{-3}}. Find the drift velocity.
1v=InAqv = \dfrac{I}{nAq}.
2Denominator: 8.5×1028×1.0×10−6×1.60×10−19=1.36×1048.5\times10^{28} \times 1.0\times10^{-6} \times 1.60\times10^{-19} = 1.36\times10^{4}.
3v=3.01.36×104v = \dfrac{3.0}{1.36\times10^{4}}.
Answerv=2.2×10−4 m s−1v = 2.2 \times 10^{-4}\ \mathrm{m\,s^{-1}} — about 0.2 mm per second.

Tip — A drift velocity of a fraction of a millimetre per second is the expected answer for a metal. Getting metres per second means nn or AA has been mishandled.

4

Why the lamp lights instantly

At that drift velocity an electron would take hours to travel the length of a mains cable, yet a lamp lights the moment the switch closes. The resolution is that the electrons do not have to travel from the switch to the lamp.

The conductor is already full of free electrons everywhere, including inside the lamp. Closing the switch establishes an electric field along the wire at close to the speed of light, and every electron in the circuit begins drifting almost simultaneously.

So what propagates quickly is the field\textbf{field}, not the charge carriers. The electrons themselves also move rapidly in random thermal motion — around 105 m s−110^{5}\ \mathrm{m\,s^{-1}} — with the drift velocity being only a tiny net bias superimposed on that chaos.

Example 1Explain why a lamp lights immediately when a switch is closed, given a drift velocity of about 10−4 m s−110^{-4}\ \mathrm{m\,s^{-1}}.
1Free electrons are already present throughout the circuit, including in the lamp.
2Closing the switch sets up an electric field along the conductor at near light speed.
3All electrons start drifting almost at once, so the lamp’s electrons move immediately.
AnswerThe electric field propagates almost instantly and the charge carriers are already everywhere, so no electron has to travel from the switch to the lamp.

Equation recap

I=ΔQΔtI = \tfrac{\Delta Q}{\Delta t}
Definition of current.
V=WQV = \tfrac{W}{Q}
Potential difference.
W=QV=IVtW = QV = IVt
Energy transferred.
I=nAvqI = nAvq
Drift velocity equation.
e=1.60×10−19 Ce = 1.60\times10^{-19}\ \mathrm{C}
Elementary charge.

Common mistakes to avoid

Saying current is "used up" by a component.
Charge is conserved and current is the same all round a series loop. Energy is what is transferred.
Treating e.m.f. as a force.
It is energy per unit charge, measured in volts. The name is historical.
Using area in mm2\mathrm{mm^{2}} in I=nAvqI = nAvq.
Convert to m2\mathrm{m^{2}} — a factor of 10610^{6} that silently wrecks the answer.
Claiming electrons travel from the switch to the lamp at high speed.
The field propagates quickly; the electrons drift slowly and are already present throughout.

Key takeaways

  • Current is rate of flow of charge, I=ΔQ/ΔtI = \Delta Q/\Delta t, measured in amperes.
  • Potential difference and e.m.f. are both energy per coulomb, differing in direction of transfer.
  • Charge is quantised in multiples of e=1.60×10−19 Ce = 1.60\times10^{-19}\ \mathrm{C}.
  • I=nAvqI = nAvq links current to carrier density, area, drift velocity and charge.
  • Lamps light instantly because the field propagates fast and carriers are already present throughout.

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