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In 1909 Geiger and Marsden fired alpha particles at gold foil. Most went straight through, but about one in several thousand bounced back. That result overturned the plum-pudding model and revealed that almost all of an atom’s mass sits in a tiny, positively charged .
What you'll be able to do
A narrow beam of alpha particles from a radioactive source was directed at a very thin gold foil in a vacuum. A movable detector — originally a zinc sulfide screen viewed through a microscope — counted scintillations at different angles.
The vacuum matters: alpha particles are strongly ionising and would be stopped within a few centimetres of air. The foil must be thin so that each alpha particle is scattered by at most one nucleus.
The observations were: most alpha particles passed straight through with little or no deflection; a small fraction were deflected through large angles; and a very small number, roughly 1 in 8000, were scattered back through more than .
Tip — Learn the three observations and pair each with its conclusion — that is how six-mark questions on this experiment are marked.
: the atom is mostly empty space.
: there is a concentration of positive charge that repels the positive alpha particles strongly.
: that charge, and most of the atom’s mass, is concentrated in a very small volume. Only a massive, compact centre could reverse an alpha particle’s motion, and the rarity of back-scattering shows how small a target it presents.
In the plum-pudding model, positive charge was spread thinly through the atom. Its field would be far too weak anywhere to deflect a fast alpha particle through a large angle, so the model could not explain the results.
For an alpha particle heading straight at a nucleus, it slows as it approaches, stops momentarily, and is pushed back. At that turning point all its initial kinetic energy has become electric potential energy.
Setting gives the distance of closest approach. The nucleus must be smaller than this, so it gives an upper limit on nuclear radius.
The charge of a nucleus with proton number is , and an alpha particle carries .
Tip — Convert MeV to joules first: .
A nucleus is written , where is the proton number and is the nucleon number (protons plus neutrons). The number of neutrons is .
are nuclei of the same element — same — with different numbers of neutrons. Carbon-12 and carbon-14 are both carbon, with 6 and 8 neutrons.
Alpha particles are limited as probes: they are affected by the strong nuclear force if they get close enough, and they cannot reach heavy nuclei at typical source energies. High-energy are better — they are not affected by the strong force, and at high energy their de Broglie wavelength is comparable to nuclear dimensions, so they diffract around nuclei and reveal their size.
The same approach, at still higher energies, showed that electrons scatter from three point-like charges inside each proton — the first evidence for quarks.
Equation recap
Common mistakes to avoid
Key takeaways
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